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Here was my solution when I discovered resent changes to my keychain weren't being updated:
I was having difficulty with my agilekeychain not syncing the latest data changes. It's not a problem with Dropbox. Open 1Password>Preferences>Advanced and then Clear Cache. Uncheck using cache to prevent this from happening again (or simply remember to clear the cache).
[From 1password AgileKeyChain is not syncing « Dropbox Forums]